The Other Women! Gisele Bündchen, Angelina Jolie, LeAnn Rimes, More Stars Who Reportedly Met Their Partners When They Were Still With Someone Else

SHARING THE SPOTLIGHT! MIRANDA LAMBERT THINKS HER HUSBAND BRENDAN MCLOUGHLIN IS 'A NATURAL IN FRONT OF THE CAMERA'

Rimes "Can't Fight the Moonlight," but she can battle with her hubby's ex, Glanville! Ever since Rimes and Cibrian hooked up in 2009 — while the actor was still married to the Real Housewives of Beverly Hills star — the ladies have been throwing barbs, with Glanville once branding the country singer a "stalker." 

In 2003, Danes fell in love with Crudup while they were shooting Stage Beauty — prompting him to leave Parker, his pregnant girlfriend of eight years! They split four years later, but Danes still defends the affair. 

"I was just in love with him and needed to explore that," she told Howard Stern in 2015, admitting that she was young and careless at the time. "I was 24... I didn't quite know what those consequences would be."

DISNEY MAGIC! SHAILENE WOODLEY & AARON RODGERS PACK ON THE PDA DURING FLORIDA VACATION — PHOTOS

Keys and the hip-hop producer had known each other since they were teenagers but didn't start dating until 2008 — while Beatz was married to singer Mashonda. 

The model was fiercely private about her relationship with the NBA player — and with good reason. Simmons reportedly started dating Jenner while he was still with Tinashe. The rumors intensified when the singer's younger brother weighed in on Twitter and accused the pro athlete of cheating on his sister and breaking her heart. Simmons' romance with Jenner wasn't a slam dunk, either. After more than a year on and off, they split for good in early 2020.

ANA DE ARMAS SPOTTED WITH MYSTERY HUNK AFTER SHUTTING DOWN RECONCILIATION RUMORS WITH EX FLING BEN AFFLECK

Portman swanned in and stole the show! In 2009, just one week before starting work on Black Swan, Millepied was snapping happy vacation pics with his live-in ballerina girlfriend, Boylston. But less than a year later, the choreographer and Portman were engaged and pregnant, with the Oscar-winning actress releasing a statement saying she was "indescribably happy and [felt] very grateful to have this experience." Boylston, probably not so much.

RIHANNA STUNS IN FRINGE AS SHE SPOTTED LEAVING EX DRAKE'S PRIVATE EVENT IN HOLLYWOOD WITH BEAU A$AP ROCKY — PHOTOS

Spears fell hard for Federline — the backup dancer she'd marry and have two children with — after meeting in 2004. But there was a problem: He was also dating Jackson! 

Jolie made headlines when she broke up Pitt and Aniston's marriage in 2005. But as it turns out, it wasn't the first time she'd come between a co-star and their partner. Back in 1999, while filming Pushing Tin, Jolie met Thornton — who was engaged to Dern. 

KOURTNEY KARDASHIAN ON TOP OF HER FAMILY'S 'BIKINI RIVALRY' AS SHE RADIATES CONFIDENCE FROM RELATIONSHIP WITH TRAVIS BARKER

When Lambert sings "We Should Be Friends," she's probably not talking to several scorned women! Evan, who the country singer dated before marrying Brendan McLoughlin, served his wife Staci divorce papers just 15 days after meeting Lambert in 2018. (They've since reconciled.) But this wasn't the Grammy winner's first rodeo: Her ex-husband, Shelton, was still with his first wife, Williams, when he fell for the "Vice" singer. It's safe to say Lambert has a type!

TAKING THE NEXT STEP? SCOTT DISICK & AMELIA HAMLIN SEEN LOOKING AT 'ENGAGEMENT RINGS,' SOURCE SPILLS — PHOTOS

"I knew right away — the first time I saw him" is how Bündchen would describe her 2006 meeting with her future NFL player hubby. What she didn't know at the time was that he was the soon-to-be baby daddy of his girlfriend of the past three years, Moynahan! 

The Blue Bloods actress and Brady split around the time he met Bündchen, but Moynahan has since said, "When you're suddenly pregnant and no one is standing by your side, even if you're in your 30s, it's a hard conversation."